Phosphorus Flame Retardant UPR (Non-Halogen)
Key Features
- Halogen-free — no HCl or dioxin on combustion
- Reactive phosphorus for permanent, non-leachable FR
- Suitable for EN 45545-2 HL2 rail certification
- Char-forming condensed-phase FR mechanism
- Can be enhanced with ATH or magnesium hydroxide fillers
Phosphorus Flame Retardant UPR is a halogen-free thermosetting resin that incorporates reactive phosphorus-containing monomers (typically phosphonate or phosphate esters) directly into the polyester backbone, supplemented by reactive phosphorus diluents in the styrene phase. This non-halogen approach meets the most stringent environmental and health requirements for closed compartment applications in rail, automotive, and building construction.
The phosphorus content (typically 1.5-3.0% P by weight) acts primarily in the condensed phase by promoting char formation, which physically insulates the underlying substrate from heat and oxygen. LOI of cured neat castings is 26-30%, and with ATH or magnesium hydroxide co-fillers, EN 45545-2 HL2 compliance is achievable for rail interior components.
Viscosity at 25°C is 350-650 mPa·s, suitable for hand lay-up, spray-up, and RTM. Cured flexural strength is 90-105 MPa. The absence of halogens eliminates toxic smoke gas generation concerns, making this the preferred choice for underground and enclosed transport infrastructure FRP applications.
Specifications
| Parameter | Value |
|---|---|
| Appearance | Pale yellow liquid |
| Halogen Content | None |
| Viscosity (25°C) | 350-650 mPa·s |
| LOI (neat casting) | 26-30% |
| Flexural Strength (cured) | 90-105 MPa |
| Phosphorus Content (cured) | 1.5-3.0% P |
| Gel Time (25°C, 1.5% MEKP) | 15-25 min |
Applications
FAQ
HL3 compliance is the most demanding category and typically requires a combination of phosphorus UPR, 40-60 phr ATH + magnesium hydroxide filler, and a fire-retardant gelcoat surface. Test configurations must be submitted to an accredited laboratory. Achieving HL3 for open-mold hand lay-up laminates is challenging; RTM or resin film infusion with higher filler loading is more practical.
Direct Contact
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