Phosphorus Flame Retardant UPR (Non-Halogen)

CAS 26455-61-8In StockSample available

Key Features

  • Halogen-free — no HCl or dioxin on combustion
  • Reactive phosphorus for permanent, non-leachable FR
  • Suitable for EN 45545-2 HL2 rail certification
  • Char-forming condensed-phase FR mechanism
  • Can be enhanced with ATH or magnesium hydroxide fillers

Phosphorus Flame Retardant UPR is a halogen-free thermosetting resin that incorporates reactive phosphorus-containing monomers (typically phosphonate or phosphate esters) directly into the polyester backbone, supplemented by reactive phosphorus diluents in the styrene phase. This non-halogen approach meets the most stringent environmental and health requirements for closed compartment applications in rail, automotive, and building construction.

The phosphorus content (typically 1.5-3.0% P by weight) acts primarily in the condensed phase by promoting char formation, which physically insulates the underlying substrate from heat and oxygen. LOI of cured neat castings is 26-30%, and with ATH or magnesium hydroxide co-fillers, EN 45545-2 HL2 compliance is achievable for rail interior components.

Viscosity at 25°C is 350-650 mPa·s, suitable for hand lay-up, spray-up, and RTM. Cured flexural strength is 90-105 MPa. The absence of halogens eliminates toxic smoke gas generation concerns, making this the preferred choice for underground and enclosed transport infrastructure FRP applications.

Specifications

ParameterValue
AppearancePale yellow liquid
Halogen ContentNone
Viscosity (25°C)350-650 mPa·s
LOI (neat casting)26-30%
Flexural Strength (cured)90-105 MPa
Phosphorus Content (cured)1.5-3.0% P
Gel Time (25°C, 1.5% MEKP)15-25 min

Applications

Rail interior FRP panels (EN 45545-2 compliant)Automotive interior composites (halogen-free)Building construction FRP (halogen-free Euroclass)Electrical enclosures requiring UL 94 V-0 (no halogen)Underground infrastructure FRP ducts and covers

FAQ

HL3 compliance is the most demanding category and typically requires a combination of phosphorus UPR, 40-60 phr ATH + magnesium hydroxide filler, and a fire-retardant gelcoat surface. Test configurations must be submitted to an accredited laboratory. Achieving HL3 for open-mold hand lay-up laminates is challenging; RTM or resin film infusion with higher filler loading is more practical.

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