Epoxy Novolac Resin F-51 (High Functionality)

CAS 28064-14-4In StockSample available

Key Features

  • High functionality (3.5-4.0 epoxides/molecule) for dense cross-linking
  • Tg 175-200°C with aromatic amine hardeners
  • Improves Tg when blended with BPA epoxy systems
  • Superior chemical resistance vs. difunctional epoxies
  • Standard FR4 PCB and aerospace prepreg modifier

Epoxy Phenol Novolac Resin F-51 is a multifunctional epoxy produced by the epoxidation of phenol-formaldehyde novolac with an average functionality of 3.5-4.0 epoxide groups per molecule. The high epoxide functionality results in a highly cross-linked network on cure, providing significantly higher Tg (150-200°C), better chemical resistance, and higher strength at elevated temperatures compared to difunctional BPA epoxies.

F-51 is available as a high-viscosity liquid or low-melting-point semi-solid (softening point 50-80°C depending on molecular weight) in xylene or other solvents for processing convenience. EEW is 175-195 g/eq. The resin is widely used in aerospace and industrial thermoset matrices, electrical laminates (particularly FR4/CEM printed circuit boards), powder coatings for pipes, and high-temperature resistant adhesives.

In prepreg applications, F-51 is blended at 15-40% loading with BPA epoxy to raise the composite Tg to 150-180°C while controlling cost. In electrical FR4 laminates, F-51 provides the high-temperature performance needed for lead-free solder reflow (Tg >150°C requirement). Chemical resistance (concentrated acid, base, solvent immersion) is superior to BPA epoxy due to higher cross-link density.

Specifications

ParameterValue
ColorAmber-brown
AppearanceAmber to brown viscous liquid or semi-solid
Tg (DDS cured)175-200°C
Viscosity (50°C)1,500-5,000 mPa·s
Average Functionality3.5-4.0
Hydrolyzable Chloride≤500 ppm
Epoxy Equivalent Weight175-195 g/eq

Applications

FR4 and high-performance PCB laminate matrix resinsAerospace composite Tg enhancement (blended with BPA)High-temperature resistant powder coatings for pipelinesElectronic encapsulation requiring high HDTChemical-resistant adhesives and coatings

FAQ

For aerospace prepreg formulations targeting Tg 150-180°C: 20-35% F-51 + 65-80% BPA epoxy (EEW 184-194) is typical. At 30% F-51, the weighted average EEW is approximately 185-188 g/eq — effectively the same as pure BPA epoxy for hardener calculation. The F-51 contributes multifunctional cross-linking that raises Tg and retains better hot/wet properties. Higher F-51 loading (>40%) increases viscosity significantly and requires processing temperature adjustment.

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