High-Temperature Aerospace Epoxy System (Tg >200°C, DDS Cure)

CAS 25068-38-6In StockSample available

Key Features

  • Tg 200-230°C — highest performance epoxy for aerospace structural applications
  • TGMDA/novolac blend for maximum cross-link density and hot/wet retention
  • Qualified for FAA/EASA primary structure certification programs
  • Outstanding hot/wet performance (>55 MPa at 180°C after conditioning)
  • Compatible with prepreg and film adhesive processing

High-Temperature Aerospace Epoxy System is a multi-component epoxy resin formulation designed to achieve Tg >200°C when cured with 4,4'-diaminodiphenylsulfone (DDS), meeting the requirements of aerospace structural composites, aircraft engine nacelle components, military aircraft structures, and high-temperature composite tooling. The system is based on a blend of BPA epoxy, tetraglycidyl-MDA (TGMDA, EEW 115-130), and epoxy novolac (F-44 or F-51 modifier) to achieve the functionality and cross-link density required for ultra-high-Tg performance.

The resin system is semi-solid or solid at room temperature and is processed as a prepreg or film adhesive with DDS dissolved/dispersed in the resin matrix. The standard cure schedule is 120°C/1h + 177°C/2h with optional post-cure at 200-220°C/1h for maximum Tg. The cured system properties include Tg 200-230°C, dry tensile strength >80 MPa, hot/wet (180°C after conditioning) tensile strength >55 MPa retention, demonstrating the outstanding hot/wet property retention critical for aerospace primary structure certification.

This system is qualified for FAA/EASA-certifiable primary structural composite applications per ASTM D5229, D3039, D6272 test protocols. Applications include aircraft fuselage structural panels, military aircraft control surfaces, jet engine nacelle and thrust reverser structures, space launch vehicle structural shells, and high-temperature composite tooling for 180°C autoclave cure.

Specifications

ParameterValue
Cure Schedule120°C/1h + 177°C/2h (+ optional 200°C/1h)
Processing FormPrepreg or solution (DDS in resin)
Tg (177°C/2h cure)190-200°C
Dry Tensile Strength>80 MPa
Qualification StandardsASTM D3039, D6272, D5229
Tg (200°C/1h post-cure)210-230°C
Hot/Wet Tensile Strength (180°C)>55 MPa

Applications

Aircraft fuselage and wing primary structural compositesJet engine nacelle and thrust reverser structures (>180°C service)Military aircraft control surfaces and structural panelsSpace launch vehicle structural composite shellsHigh-temperature composite tooling (180°C autoclave)

FAQ

TGMDA (tetraglycidyl-4,4'-methylenedianiline, also known as TGDDM, EEW 115-130 g/eq) is a tetrafunctional aromatic epoxy monomer providing four epoxide groups per molecule. When blended with DDS (tetrafunctional amine) and cured at 177°C, the 4-functional epoxy + 4-functional amine crosslinking creates an extremely dense, highly crosslinked network with Tg 200-230°C and outstanding hot/wet retention. TGMDA is the primary resin in most commercial aerospace 177°C-cure epoxy systems (Hexion EPON 1031, Huntsman Araldite MY721) and is the baseline for T300/5208, T300/914, AS4/3501-6, and similar commercially qualified aerospace composite systems.

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