Lauroyl Peroxide (LPO, 98% Purity)

CAS 105-74-8In StockSample available

Key Features

  • Low 10-hr T½ (~62°C) enables cure at 50–80°C processing temperatures
  • Lower odor and cleaner decomposition products vs. BPO
  • Suitable for continuous lamination line applications
  • Good solubility in styrene and reactive diluents
  • Effective initiator for acrylic polymerization

Lauroyl Peroxide (LPO) is a diacyl peroxide with a 10-hour half-life temperature of approximately 62°C, making it one of the most reactive solid peroxides available for low-temperature thermal cure of unsaturated polyester, acrylic, and vinyl ester resins. LPO generates lauroyloxy and undecyl radicals upon thermal decomposition, initiating free-radical polymerization efficiently at 50–80°C. Its relatively low half-life temperature makes it valuable in applications where full cure must be achieved at low oven temperatures, such as in continuous lamination lines, SMC maturation, and low-energy cure cycles. LPO can also be activated with amine accelerators for ambient-temperature cure, similar to BPO, though it is less commonly used in this mode. The 98% purity grade is a waxy white solid with a faint odor. Decomposition products include dodecane and CO2, which are relatively benign compared to BPO's phenyl radical products. LPO is used at dosage levels of 1–3% on resin in thermal cure applications. Store below 15°C to prevent premature decomposition.

Specifications

ParameterValue
AppearanceWhite waxy solid
LPO Purity≥98%
Shelf Life12 months at ≤15°C
Melting Range53–57°C
Active Oxygen Content≥3.9%
10-hr Half-Life Temperature~62°C

Applications

Low-temperature thermal cure of UPR and vinyl ester laminates (50–80°C)Continuous lamination and flat sheet production linesSMC compression molding at reduced cure temperaturesAcrylic (PMMA) bulk polymerization and castingLow-energy cure cycles in press or oven molding

FAQ

LPO has a lower 10-hour half-life temperature (~62°C) compared to BPO (~73°C), making it more active at lower processing temperatures. This makes LPO preferable for low-energy thermal cure cycles and continuous lamination at 50–70°C. BPO is typically used at 80–120°C. Choose LPO when minimizing cure temperature is a priority.

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