Potassium Octoate (Accelerator for Latent)

CAS 3164-85-0In StockSample available

Key Features

  • Metal carboxylate catalyst suitable for anhydride-epoxy acceleration
  • Non-cobalt, non-amine — no risk of cobalt or amine contamination
  • Effective PIR foam trimerization catalyst
  • Synergistic with tertiary amine accelerators (BDMA, DMP-30)
  • Liquid form for easy incorporation into resin formulations

Potassium Octoate (potassium 2-ethylhexanoate) is a metal carboxylate accelerator used in anhydride-cured and DICY-based epoxy systems, and as a catalyst for isocyanate-polyol reactions in polyurethane formulations. In epoxy systems, potassium octoate acts as a nucleophilic catalyst promoting the anhydride-hydroxyl and anhydride-epoxy reactions, providing acceleration particularly effective in combination with tertiary amines such as BDMA or DMP-30. In polyurethane foam and elastomer systems, potassium octoate is a potent trimerization catalyst (promoting isocyanurate ring formation) and blowing catalyst when used in PIR (polyisocyanurate) rigid foam applications. In composite manufacturing, its primary use is as a co-catalyst in anhydride-epoxy electrical potting systems where precise control of the anhydride-epoxy esterification rate is needed. Potassium octoate is supplied as a clear, viscous solution (typically 50–80% in a carrier solvent or reactive diluent) and is fully miscible with epoxy and anhydride systems. Dosage in epoxy systems is typically 0.1–0.5% by weight. It is non-amine and non-cobalt, making it useful in applications where amine or cobalt contamination would be undesirable.

Specifications

ParameterValue
AppearanceClear to pale yellow liquid solution
Shelf Life18 months in sealed container
MiscibilityFully miscible with epoxy/anhydride
Active Content50–80% in carrier
Density (20°C)0.90–1.00 g/cm³
Potassium Content~8.5% as K

Applications

Co-catalyst in anhydride-epoxy electrical potting and castingPIR (polyisocyanurate) rigid foam trimerization catalystAccelerator in DICY-based one-component epoxy systemsCatalyst for isocyanate trimerization in structural foamsNon-amine co-accelerator in epoxy encapsulant formulations

FAQ

Potassium octoate provides potassium ions that act as Lewis acid catalysts, activating the carbonyl of the anhydride toward nucleophilic attack by hydroxyl groups (from epoxy ring opening products). The potassium carboxylate also acts as a nucleophile, opening the epoxy ring to form a zwitterionic intermediate that initiates the alternating anhydride-epoxy chain propagation. The combination of Lewis acid activation and nucleophilic initiation makes it more effective than amine-only catalysis in certain anhydride systems.

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