Isophthalic UPR (Marine Grade)

CAS 26455-61-8In StockSample available

Key Features

  • Superior hydrolytic resistance versus orthophthalic grades
  • Significantly reduced osmotic blistering tendency
  • Higher HDT for improved heat resistance in service
  • Accepted by major marine classification societies
  • Excellent compatibility with NPG gelcoat barrier systems

Isophthalic Unsaturated Polyester Resin (Marine Grade) is formulated using isophthalic acid as the primary diacid component, replacing the orthophthalic acid used in general-purpose grades. This structural modification produces a resin with significantly superior hydrolytic resistance, making it the preferred choice for marine hull construction, boat deck laminates, and any application involving prolonged water immersion.

The isophthalic backbone provides tighter polymer packing and reduced ester group density compared to orthophthalic resins, resulting in water absorption values typically 50% lower. Osmotic blistering, a common failure mode in marine FRP, is dramatically reduced when this resin is used in conjunction with an NPG isophthalic gelcoat barrier coat system.

Viscosity at 25°C is 250-500 mPa·s, compatible with hand lay-up, spray-up, and light RTM applications. The cured laminate delivers a flexural modulus of 3.8-4.2 GPa and HDT of approximately 65-75°C under standard cure conditions, rising to 80-90°C with post-cure at 80°C for 2 hours. Widely specified by Lloyd's Register, Bureau Veritas, and other classification societies for marine composite construction.

Specifications

ParameterValue
Acid Value12-20 mg KOH/g
AppearanceClear to pale yellow liquid
Density (25°C)1.12-1.14 g/cm³
Styrene Content33-38%
Viscosity (25°C)250-500 mPa·s
Water Absorption (24h)≤0.3%
HDT (post-cured 80°C/2h)80-90°C
Gel Time (25°C, 1.5% MEKP)18-28 min

Applications

Marine hull and deck laminatesBoat superstructures and bulkheadsSwimming pools and water tanksOffshore FRP structuresChemical storage vessels (moderate service)

FAQ

Isophthalic UPR absorbs approximately 50% less water than orthophthalic grades due to the more symmetrical and less hydrophilic isophthalate backbone. In marine hull testing (ISO 175 immersion, 40°C seawater), isophthalic laminates show far lower weight gain and virtually no osmotic blistering when used with a compatible NPG gelcoat. Most boat builders specify isophthalic resin for the structural laminate behind the gelcoat as standard practice.

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