DCPD High-Stiffness UPR

CAS 68411-01-8In StockSample available

Key Features

  • Highest modulus in the DCPD UPR product range (4.5-5.0 GPa)
  • Low styrene (<30%) for VOC compliance
  • Excellent surface cure properties
  • Improved HDT vs. standard orthophthalic grades
  • Consistent properties for certified structural applications

DCPD High-Stiffness UPR is a premium dicyclopentadiene-modified unsaturated polyester formulated with a high DCPD incorporation level to maximize the stiffness and modulus of cured composites while maintaining low styrene content (<30%). The bicyclic DCPD ring structure, once incorporated into the polyester backbone, creates a rigid, bulky polymer chain that is highly resistant to deformation under load.

The high DCPD loading delivers a flexural modulus of 4.5-5.0 GPa in fiber-free castings and 28-38 GPa in pultruded profiles at 60% glass content. This represents a 15-25% improvement in stiffness over standard orthophthalic UPR, beneficial for structural applications where deflection is the critical design criterion. HDT is also improved to 70-80°C due to the rigid DCPD segments.

Viscosity at 25°C is 150-300 mPa·s, well-suited for pultrusion and filament winding. Surface cure properties are excellent due to the inherent DCPD surface activity that reduces surface tack. The resin delivers consistent mechanical properties with low batch-to-batch variability, critical for certified structural applications including construction profiles, utility poles, and road infrastructure components.

Specifications

ParameterValue
AppearanceClear to slightly hazy liquid
HDT (cured)70-80°C
Styrene Content<30%
Viscosity (25°C)150-300 mPa·s
Gel Time (25°C, BPO/TBPB)Via die cure
Flexural Modulus (cast, cured)4.5-5.0 GPa
Flexural Modulus (60% glass, pultruded)28-38 GPa

Applications

High-stiffness pultruded structural profilesUtility poles and transmission line supportsBridge beam and deck slab FRP structuresHigh-modulus FRP road infrastructure componentsStiff antenna radomes and structural panels

FAQ

DCPD contains a fused bicyclic ring system (norbornene + cyclopentadiene) that, when incorporated into the polyester via Diels-Alder reaction with maleic anhydride, adds bulky, rigid ring segments to the backbone. These cycloaliphatic rings restrict chain mobility and raise the glass transition temperature, resulting in higher stiffness (modulus) and improved creep resistance compared to flexible linear-chain ortho or iso-UPR. The effect is proportional to DCPD incorporation level.

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