Brominated Epoxy Resin (Tetrabromobisphenol A Diglycidyl Ether)
Key Features
- ~48-50% bromine — highest reactive FR efficiency in epoxy systems
- Reactive incorporation: permanent, non-migrating flame retardancy
- Standard component for UL94 V-0 FR4 PCB laminates
- Compatible with DICY cure systems for FR4 manufacturing
- Covalent flame retardancy — no bloom or migration risk
Brominated Epoxy Resin (TBBPA-DGE, CAS 26265-08-7) is the diglycidyl ether of tetrabromobisphenol A, containing approximately 48-50 wt% bromine. This reactive flame retardant epoxy resin is the standard component for achieving UL94 V-0 flame retardancy in epoxy laminate systems, particularly FR4 printed circuit board base materials (IPC-4101 specification), halogenated flame retardant epoxy composites, and electrical encapsulation requiring UL94 V-0 classification.
In FR4 PCB laminates, brominated epoxy is blended with standard BPA epoxy at 25-40% loading to achieve the bromine content (18-21 wt% in cured laminate) required for UL94 V-0 classification. The EEW of 340-380 g/eq reflects the molecular weight contribution of the four bromine atoms. The resin is compatible with DICY/accelerator cure systems standard in FR4 manufacturing and produces laminates meeting IPC-4101C Class B/L specifications for glass-reinforced epoxy laminates.
Beyond PCB applications, brominated epoxy is used in transformer potting compounds requiring UL94 V-0, flame-retardant composite structures (mass transportation, building panels), and halogenated epoxy adhesives for fire-rated assemblies. The reactive nature of the flame retardant (covalently incorporated versus additive FR) ensures permanent flame retardancy not subject to migration or extraction.
Specifications
| Parameter | Value |
|---|---|
| Appearance | Viscous liquid to semi-solid (pale yellow) |
| Bromine Content | 48-50 wt% |
| Color (Gardner) | ≤3 |
| Viscosity (70°C) | 500-3,000 mPa·s |
| Hydrolyzable Chloride | ≤500 ppm |
| Epoxy Equivalent Weight | 340-380 g/eq |
| Flame Retardancy (blended system) | UL94 V-0 |
Applications
FAQ
UL94 V-0 in glass/epoxy FR4 laminates requires approximately 18-21 wt% bromine in the cured resin matrix. Using brominated epoxy at 48-50 wt% Br: blending 35-40 parts brominated epoxy + 60-65 parts BPA epoxy (by weight) achieves the target bromine level. Weighted average calculation: 40 parts × 49% Br = 19.6 wt% Br in the blend — sufficient for UL94 V-0. The weighted average EEW = (0.40×360) + (0.60×189) = 144 + 113.4 = 257.4 g/eq, used for DICY hardener stoichiometry.
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