Brominated Epoxy Resin (Tetrabromobisphenol A Diglycidyl Ether)

CAS 26265-08-7In StockSample available

Key Features

  • ~48-50% bromine — highest reactive FR efficiency in epoxy systems
  • Reactive incorporation: permanent, non-migrating flame retardancy
  • Standard component for UL94 V-0 FR4 PCB laminates
  • Compatible with DICY cure systems for FR4 manufacturing
  • Covalent flame retardancy — no bloom or migration risk

Brominated Epoxy Resin (TBBPA-DGE, CAS 26265-08-7) is the diglycidyl ether of tetrabromobisphenol A, containing approximately 48-50 wt% bromine. This reactive flame retardant epoxy resin is the standard component for achieving UL94 V-0 flame retardancy in epoxy laminate systems, particularly FR4 printed circuit board base materials (IPC-4101 specification), halogenated flame retardant epoxy composites, and electrical encapsulation requiring UL94 V-0 classification.

In FR4 PCB laminates, brominated epoxy is blended with standard BPA epoxy at 25-40% loading to achieve the bromine content (18-21 wt% in cured laminate) required for UL94 V-0 classification. The EEW of 340-380 g/eq reflects the molecular weight contribution of the four bromine atoms. The resin is compatible with DICY/accelerator cure systems standard in FR4 manufacturing and produces laminates meeting IPC-4101C Class B/L specifications for glass-reinforced epoxy laminates.

Beyond PCB applications, brominated epoxy is used in transformer potting compounds requiring UL94 V-0, flame-retardant composite structures (mass transportation, building panels), and halogenated epoxy adhesives for fire-rated assemblies. The reactive nature of the flame retardant (covalently incorporated versus additive FR) ensures permanent flame retardancy not subject to migration or extraction.

Specifications

ParameterValue
AppearanceViscous liquid to semi-solid (pale yellow)
Bromine Content48-50 wt%
Color (Gardner)≤3
Viscosity (70°C)500-3,000 mPa·s
Hydrolyzable Chloride≤500 ppm
Epoxy Equivalent Weight340-380 g/eq
Flame Retardancy (blended system)UL94 V-0

Applications

FR4 PCB laminate (UL94 V-0, IPC-4101C Class B/L)Flame-retardant epoxy composites for mass transportationTransformer and electrical encapsulation (UL94 V-0)Halogenated flame-retardant adhesives for fire-rated assembliesBuilding panel and construction composite flame retardancy

FAQ

UL94 V-0 in glass/epoxy FR4 laminates requires approximately 18-21 wt% bromine in the cured resin matrix. Using brominated epoxy at 48-50 wt% Br: blending 35-40 parts brominated epoxy + 60-65 parts BPA epoxy (by weight) achieves the target bromine level. Weighted average calculation: 40 parts × 49% Br = 19.6 wt% Br in the blend — sufficient for UL94 V-0. The weighted average EEW = (0.40×360) + (0.60×189) = 144 + 113.4 = 257.4 g/eq, used for DICY hardener stoichiometry.

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