Bisphenol F Liquid Epoxy Resin (EEW 155-170)

CAS 9003-36-5In StockSample available

Key Features

  • 3-5× lower viscosity than BPA epoxy at equal temperature
  • Higher epoxy functionality (lower EEW) for superior cross-linking
  • Excellent electrical insulation properties
  • Does not crystallize at low storage temperatures
  • Reactive diluent for BPA epoxy viscosity reduction

Bisphenol F Liquid Epoxy Resin (EEW 155-170 g/eq) is produced by the condensation of bisphenol F (4,4'-dihydroxydiphenylmethane) with epichlorohydrin. Compared to bisphenol A epoxy (EEW 184-194), bisphenol F epoxy has a significantly lower viscosity (2,000-4,500 mPa·s at 25°C) due to the lack of geminal methyl groups on the central carbon, resulting in a less symmetric, more flexible backbone that crystallizes less readily at low temperatures.

The lower viscosity of BPF epoxy makes it the preferred choice for low-temperature applications, high-solids coating formulations, solventless systems, and neat resin casting where BPA epoxy would be too viscous. EEW of 155-170 g/eq (higher epoxy content than BPA) enables slightly lower curing agent dosages and potentially higher cross-link density.

Cured BPF epoxy with aromatic amines (DDS, DDM) provides Tg 150-175°C and chemical resistance equivalent to or slightly superior to BPA epoxy. In composite applications, BPF epoxy is used as a reactive diluent for BPA epoxy blends to reduce viscosity without introducing non-reactive species. Electrical encapsulation and transformer casting grades are a major application area for BPF due to its excellent electrical properties and low viscosity at processing temperatures.

Specifications

ParameterValue
AppearanceClear to very slightly yellow liquid
Epoxy Value0.59-0.65 eq/100g
Color (Gardner)≤1
Density (25°C)1.19-1.20 g/cm³
Viscosity (25°C)2,000-4,500 mPa·s
Hydrolyzable Chloride≤500 ppm
Epoxy Equivalent Weight155-170 g/eq

Applications

High-solids and solventless protective coatingsElectrical transformer and busbar casting and pottingLow-temperature application coatings (<5°C ambient)Reactive viscosity reducer blended with BPA epoxyHigh-performance flooring and self-leveling epoxy systems

FAQ

BPF epoxy replaces the isopropylidene bridge (C(CH3)2) of BPA with a methylene bridge (CH2), making it slightly more reactive and less viscous due to lower molecular symmetry and less hindered epoxide groups. All standard curing agents (aliphatic amines, aromatic amines, anhydrides, DICY) are fully compatible with BPF epoxy using the same stoichiometric calculation (per EEW). BPF/BPA blends behave as a single epoxy component for stoichiometry purposes, calculated on the weighted average EEW.

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