DCPD-Modified Vinyl Ester Resin

CAS 3066-71-5In StockSample available

Key Features

  • Low styrene (<30%) for reduced VOC emissions
  • Retains vinyl ester chemical resistance
  • Excellent surface cure — non-tacky finish
  • Suitable for open-mold processes in regulated environments
  • Lower styrene odor vs. standard vinyl ester

DCPD-Modified Vinyl Ester Resin combines the chemical resistance of a standard bisphenol A vinyl ester backbone with DCPD modification to reduce styrene content below 30%, lower VOC emissions, and improve surface cure properties while maintaining the superior toughness, elongation, and corrosion resistance characteristic of vinyl ester resins.

The DCPD modification reduces the reactive double bond density in the polymer chain (replacing some maleate sites), lowering styrene demand and providing the characteristic waxy surface cure layer that prevents surface tack. This makes it particularly suitable for open-mold fabrication environments with VOC restrictions where vinyl ester chemical resistance is still required.

Mechanical properties are slightly reduced versus standard BPA vinyl ester: flexural strength 130-160 MPa, elongation 2-4%. Chemical resistance is maintained at BPA vinyl ester level for most media. Viscosity at 25°C is 200-400 mPa·s. HDT after post-cure at 80°C/2h is 90-110°C. Applications include hand lay-up marine structures, chemical plant open-mold panels, and any application combining low styrene requirements with vinyl ester performance.

Specifications

ParameterValue
AppearanceClear to slightly hazy liquid
Styrene Content<30%
Viscosity (25°C)200-400 mPa·s
Chemical ResistanceEquivalent to BPA VER
Flexural Strength (cured)130-160 MPa
HDT (post-cured 80°C/2h)90-110°C
Gel Time (25°C, 1.5% MEKP)20-35 min

Applications

Low-VOC open-mold marine structuresChemical plant FRP panels (open-mold, low emission)Hand lay-up chemical resistant liningsAnti-corrosion FRP in low styrene emission zonesSpray-up corrosion-resistant FRP structures

FAQ

Yes, the BPA epoxy backbone of the vinyl ester is largely retained in DCPD-modified grades — the DCPD replaces some of the styrene cross-link density but does not fundamentally change the hydrolysis-resistant ether/methacrylate character of the vinyl ester. Water absorption values are typically within 0.05-0.10 percentage points of standard BPA vinyl ester, well within marine barrier coat performance requirements.

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