Flexibilized Epoxy System (High Elongation, Impact-Resistant)

CAS 25068-38-6In StockSample available

Key Features

  • High elongation at break (15-50%) for impact and peel resistance
  • High peel strength (3-8 N/mm) — far superior to rigid epoxy
  • Accommodates differential thermal expansion between dissimilar materials
  • Maintains flexibility at low temperature (to -40°C)
  • Compatible with polyamide and polyamidoamine hardeners

Flexibilized Epoxy System is a modified two-part epoxy resin/hardener designed to produce cured compositions with high elongation at break (15-50%), excellent impact resistance, and outstanding adhesion to rigid and flexible substrates. The flexibility is achieved through combination of aliphatic epoxy components (polypropylene glycol diglycidyl ether, NPGDGE), flexibilizing BPA adducts, and polyamide or polyamidoamine hardeners that introduce a flexible backbone into the cured network.

Unlike rigid structural epoxies, flexibilized epoxy systems resist crack initiation under impact and peel loading conditions. Lap shear strength is maintained at 12-20 MPa while peel strength reaches 3-8 N/mm — significantly higher than rigid epoxy systems (typically <1 N/mm peel). This combination makes flexibilized epoxies suitable for bonding substrates with differential thermal expansion, flexible electronics, wearable device assembly, and vibration-damping structural applications.

Key applications include flexible encapsulation and coating of electronic assemblies on flexible PCBs, bonding of metal brackets to composite aircraft panels (thermal expansion mismatch), automotive glass bonding (windshield to frame with thermal cycling), industrial gasketing compounds, and flexible pipe repair composites. The system achieves Shore D hardness of 55-75 after cure at ambient temperature, with tensile strength 10-25 MPa and elongation at break 15-50% depending on hardener ratio.

Specifications

ParameterValue
Tg0 to -30°C (rubbery) to 40-60°C (semi-rigid)
Shore D Hardness55-75
Tensile Strength10-25 MPa
Elongation at Break15-50% (grade dependent)
Peel Strength (T-peel)3-8 N/mm
Lap Shear Strength (Al)12-20 MPa
Mixed Viscosity (25°C)2,000-10,000 mPa·s

Applications

Flexible encapsulation of electronics on flexible PCBsBonding dissimilar materials with thermal expansion mismatchAutomotive windshield and glass bonding (thermal cycling)Flexible pipe repair composite systemsVibration-damping structural bonding

FAQ

Flexibilized epoxy modifies the base network by incorporating flexible chain segments (polyether diols, fatty acid polyamide hardeners) into the crosslinked structure — the entire network becomes more flexible, resulting in lower modulus and higher elongation throughout. CTBN (carboxyl-terminated butadiene-nitrile, epoxy-toughened-ctbn) toughens epoxy by creating a discrete rubber phase (micron-scale particles) within a rigid epoxy matrix through phase separation during cure. CTBN-toughened epoxy retains higher modulus and tensile strength than flexibilized epoxy while improving impact resistance via crack-tip energy absorption by rubber particles. For applications requiring both high stiffness and toughness (structural adhesives, aerospace composites), CTBN toughening is preferred. For applications requiring high elongation and peel strength (sealants, flexible encapsulation), flexibilized epoxy is preferred.

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