3-Aminopropyltrimethoxysilane (KH-540 / APTMS)
Key Features
- Trimethoxy groups hydrolyze 3–5× faster than triethoxysilane KH-550 — ideal for waterborne systems
- Primary amine functionality reactive with epoxy, isocyanate, anhydride, and aldehyde groups
- Preferred grade for glass fiber sizing in PA6/PA66 automotive composites
- Effective in aqueous slurry filler treatment at ambient temperature
- Same amino bonding chemistry as KH-550 with faster interface kinetics
3-Aminopropyltrimethoxysilane (APTMS, KH-540) is the trimethoxy analogue of the widely used KH-550 (APTES). Replacing ethoxy groups with methoxy groups accelerates hydrolysis by approximately 3–5×, making KH-540 the preferred grade for waterborne systems, moisture-curing adhesives, and applications where fast surface condensation is required. Both grades carry the same 3-aminopropyl functional group and deliver equivalent bonding chemistry to KH-550, but KH-540's faster reactivity profile suits different formulation constraints.
In glass fiber sizing for polyamide (nylon PA6, PA66) composites, KH-540 is widely specified because the faster methoxy hydrolysis aligns with high-speed sizing bath conditions and promotes rapid silanol formation on glass surfaces before drying. Glass fiber treated with KH-540 shows consistently high dry and retained ILSS values in PA composites, along with improved resistance to hydrothermal aging — a critical requirement for automotive structural parts exposed to under-hood humidity and temperatures.
For mineral filler surface treatment, KH-540 is preferred when the filler is treated in aqueous slurry or when fast coupling at low temperatures is required. Common substrates include kaolin, wollastonite, calcined alumina, and glass beads for engineering thermoplastic compounds. KH-540 is also used as a primer and adhesion promoter in waterborne polyurethane, epoxy, and acrylic coatings on glass and ceramic substrates, where its fast hydrolysis ensures effective surface coverage before the waterborne binder floods the interface.
Specifications
| Parameter | Value |
|---|---|
| Purity | ≥ 97.0% |
| Appearance | Colorless to pale yellow liquid |
| CAS Number | 13822-56-5 |
| Flash point | 96°C |
| Boiling point | 215°C |
| Chemical name | 3-Aminopropyltrimethoxysilane |
| Density (20°C) | 1.010–1.015 g/cm³ |
| Molecular weight | 179.3 g/mol |
| Molecular formula | C₆H₁₇NO₃Si |
| Refractive index (20°C) | 1.422–1.426 |
Applications
FAQ
Both carry identical 3-aminopropyl functional groups and produce the same chemical bonds with inorganic substrates and organic polymers. The difference is kinetics: KH-540's methoxy groups hydrolyze 3–5× faster than KH-550's ethoxy groups, releasing methanol rather than ethanol. In practice, KH-540 is preferred for (1) waterborne formulations where fast hydrolysis before coating application is critical, (2) aqueous slurry filler treatment at ambient temperature, and (3) high-speed glass fiber sizing lines. KH-550 is preferred for (1) solventborne or neat-liquid primer applications where slower hydrolysis allows better pot life, and (2) applications sensitive to methanol release. Performance in dry composite mechanical properties is essentially equivalent.
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