3-Aminopropyltriethoxysilane (A-1100 / KH-550)
Key Features
- Primary amine group reacts directly with epoxy resins — ideal epoxy composite coupling agent
- Highest wet ILSS in glass-fiber epoxy among all silane types
- Also acts as cure accelerator in fiber-matrix interface zone
- Broad mineral filler compatibility for epoxy potting and structural adhesives
- Aqueous stable — forms stable solutions at pH 3–5 for aqueous fiber sizing
3-Aminopropyltriethoxysilane (APTES, A-1100/KH-550) is a primary amine-functional organosilane coupling agent widely used for glass fiber sizing and mineral filler treatment in epoxy resin systems. The primary amine group (–NH₂) reacts directly with epoxy groups during cure, integrating the silane into the cured matrix and forming a strong, durable chemical bond at the resin-reinforcement interface.
A-1100 is particularly effective in epoxy composite systems due to its direct chemical reactivity with epoxy resins. In glass-fiber-reinforced epoxy, aminosilane-sized glass fibers consistently show the highest dry and wet interlaminar shear strength among all silane types. The amine group also acts as a latent curing agent for epoxy, meaning A-1100 on the glass surface slightly accelerates cure in the fiber-matrix interface zone, which improves adhesion.
For mineral filler treatment (wollastonite, kaolin, silica), A-1100 at 0.5–1.5% on filler weight provides a primary amine surface that acts as a reactive coupling site for epoxy matrix systems. This application is critical in epoxy casting compounds, potting compounds, and structural adhesives where high-temperature, wet, or vibration loading might otherwise delaminate untreated filler particles from the matrix. A-1100 is also used in aqueous systems as a surface primer for glass bonding and as an intermediate primer promoting adhesion between inorganic and organic layers.
Specifications
| Parameter | Value |
|---|---|
| Purity | ≥ 98.0% |
| Appearance | Colorless to light yellow liquid |
| CAS Number | 919-30-2 |
| Flash point | 95°C |
| Boiling point | 217°C |
| Chemical name | 3-Aminopropyltriethoxysilane |
| Density (20°C) | 0.942–0.948 g/cm³ |
| pH (1% aqueous) | 9.5–10.5 |
| Molecular weight | 221.4 g/mol |
| Molecular formula | H₂N(CH₂)₃Si(OC₂H₅)₃ |
Applications
FAQ
Both A-1100 (aminosilane) and A-187 (glycidoxysilane) are good coupling agents for epoxy. A-1100 is generally preferred for glass fiber sizing because: (1) the primary amine provides a self-catalyzing effect at the fiber surface, accelerating local epoxy cure and improving interfacial properties; (2) amino-silanes produce higher wet ILSS in published comparative data; (3) A-1100 hydrolyzes well in the aqueous sizing bath conditions typical for glass fiber production. A-187 is preferred for mineral filler treatment where pot life is important.
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