3-Aminopropyltriethoxysilane (A-1100 / KH-550)

CAS 919-30-2In StockSample available

Key Features

  • Primary amine group reacts directly with epoxy resins — ideal epoxy composite coupling agent
  • Highest wet ILSS in glass-fiber epoxy among all silane types
  • Also acts as cure accelerator in fiber-matrix interface zone
  • Broad mineral filler compatibility for epoxy potting and structural adhesives
  • Aqueous stable — forms stable solutions at pH 3–5 for aqueous fiber sizing

3-Aminopropyltriethoxysilane (APTES, A-1100/KH-550) is a primary amine-functional organosilane coupling agent widely used for glass fiber sizing and mineral filler treatment in epoxy resin systems. The primary amine group (–NH₂) reacts directly with epoxy groups during cure, integrating the silane into the cured matrix and forming a strong, durable chemical bond at the resin-reinforcement interface.

A-1100 is particularly effective in epoxy composite systems due to its direct chemical reactivity with epoxy resins. In glass-fiber-reinforced epoxy, aminosilane-sized glass fibers consistently show the highest dry and wet interlaminar shear strength among all silane types. The amine group also acts as a latent curing agent for epoxy, meaning A-1100 on the glass surface slightly accelerates cure in the fiber-matrix interface zone, which improves adhesion.

For mineral filler treatment (wollastonite, kaolin, silica), A-1100 at 0.5–1.5% on filler weight provides a primary amine surface that acts as a reactive coupling site for epoxy matrix systems. This application is critical in epoxy casting compounds, potting compounds, and structural adhesives where high-temperature, wet, or vibration loading might otherwise delaminate untreated filler particles from the matrix. A-1100 is also used in aqueous systems as a surface primer for glass bonding and as an intermediate primer promoting adhesion between inorganic and organic layers.

Specifications

ParameterValue
Purity≥ 98.0%
AppearanceColorless to light yellow liquid
CAS Number919-30-2
Flash point95°C
Boiling point217°C
Chemical name3-Aminopropyltriethoxysilane
Density (20°C)0.942–0.948 g/cm³
pH (1% aqueous)9.5–10.5
Molecular weight221.4 g/mol
Molecular formulaH₂N(CH₂)₃Si(OC₂H₅)₃

Applications

Glass fiber sizing for epoxy structural composites (aerospace, wind, marine)Surface treatment of wollastonite, kaolin, and silica in epoxy systemsAdhesion promoter in epoxy structural adhesives for composite bondingPrimer for glass, metal, and ceramic bonding with epoxy adhesivesMineral filler treatment for hot-wet service epoxy composites

FAQ

Both A-1100 (aminosilane) and A-187 (glycidoxysilane) are good coupling agents for epoxy. A-1100 is generally preferred for glass fiber sizing because: (1) the primary amine provides a self-catalyzing effect at the fiber surface, accelerating local epoxy cure and improving interfacial properties; (2) amino-silanes produce higher wet ILSS in published comparative data; (3) A-1100 hydrolyzes well in the aqueous sizing bath conditions typical for glass fiber production. A-187 is preferred for mineral filler treatment where pot life is important.

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