N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane (A-1120)
Key Features
- Diamine functionality (primary + secondary amine) — higher crosslink density at interface
- Superior long-term wet strength retention in glass fiber epoxy vs. A-1100
- Preferred for wind blade, aerospace, and marine structural epoxy composites
- Higher amine equivalent weight provides stronger epoxy reactivity
- Also suitable as a curing agent additive in thin-film epoxy adhesive systems
A-1120 is a diamine-functional organosilane coupling agent containing both a primary amine and a secondary amine in its functional chain. This diamine structure provides two reactive sites per molecule for reaction with epoxy groups, yielding a higher crosslink density at the filler-resin interface compared to monoamine silanes like A-1100. The higher amine functionality per molecule makes A-1120 a more potent coupling agent for demanding epoxy applications.
The diamine structure of A-1120 contributes significantly higher basicity compared to A-1100, making it the preferred silane for glass fiber sizing in high-performance epoxy composites where maximum wet strength retention is critical. In wind turbine blade composites and aerospace structures, A-1120-sized glass fiber typically outperforms A-1100-sized fiber in long-term hydrothermal aging, providing better interlaminar shear strength retention after extended hot-wet conditioning.
For mineral filler and substrate treatment, A-1120 provides enhanced reactivity with epoxy systems, producing more fully crosslinked interfacial zones. This can improve impact resistance and fatigue life of filled epoxy composites beyond what monoamine silanes achieve. A key consideration is the higher viscosity of A-1120 compared to A-1100 and its strong tendency to form self-condensation products in the presence of moisture — careful storage and handling in sealed containers under nitrogen are essential.
Specifications
| Parameter | Value |
|---|---|
| Purity | ≥ 97.0% |
| Appearance | Colorless to yellow liquid |
| CAS Number | 1760-24-3 |
| Flash point | 120°C |
| Boiling point | 259°C |
| Chemical name | N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane |
| Density (20°C) | 1.020–1.030 g/cm³ |
| pH (1% aqueous) | 10.5–11.5 |
| Molecular weight | 222.4 g/mol |
Applications
FAQ
Yes. A-1120 dissolves readily in dilute acetic acid-acidified water (pH 4–5) to form a stable aqueous solution. It is hydrolyzed in this acidic environment and applied to glass fiber in continuous sizing operations. Sizing bath concentration is typically 0.1–0.5% silane. A-1120 solutions should be used within 24–48 hours of preparation as the hydrolyzed silane can self-condense over time, reducing effectiveness.
Direct Contact
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