Wollastonite Acicular (High Aspect Ratio)
Key Features
- High aspect ratio (20:1–30:1) for near-fiber-level reinforcing efficiency
- 40–70% flexural modulus improvement at 20–40 wt% in UPR/epoxy
- Superior crack bridging and fracture toughness improvement
- Better dimensional stability and shrinkage control vs. short fiber grade
- Silane surface treatment available for maximum stress transfer efficiency
High-aspect-ratio acicular wollastonite features length-to-diameter ratios of 20:1 to 30:1, significantly exceeding the reinforcing efficiency of standard short-fiber wollastonite. This extreme needle-like morphology enables load transfer mechanisms approaching those of short glass fiber while retaining the processing advantages and cost benefits of mineral fillers.
At L/D ratios of 20:1 or higher, wollastonite needles can achieve flexural modulus improvements of 40–70% in UPR and epoxy systems at 20–40 wt% loading, with tensile strength improvements of 20–35%. The high aspect ratio also provides superior dimensional stability and shrinkage reduction compared to standard grades, which is critical in precision-molded engineering composites and structural panels.
Acicular wollastonite's reinforcing mechanism is analogous to short glass fiber: under tensile loading, the long needles bridge micro-cracks and redistribute stress, delaying crack propagation and improving fracture toughness. This makes high-aspect-ratio wollastonite valuable in FRP profiles for construction, structural pultrusion compounds, and injection-molded engineering composites where impact resistance alongside stiffness is required. Surface treatment with aminosilane is recommended to maximize stress transfer efficiency between the wollastonite surface and the resin matrix.
Specifications
| Parameter | Value |
|---|---|
| Appearance | White needle-like crystals |
| Mohs hardness | 4.5–5.0 |
| BET surface area | 4–8 m²/g |
| CaSiO₃ content | ≥ 97% |
| Moisture content | ≤ 0.3% |
| Whiteness (R457) | ≥ 92% |
| Aspect ratio (L/D) | 20:1 – 30:1 |
| pH (5% suspension) | 9.5–10.5 |
| Median fiber length | ~100–150 µm |
| Median fiber diameter | ~5–8 µm |
Applications
FAQ
Higher aspect ratio wollastonite provides better reinforcement efficiency, up to a point. L/D 20:1–30:1 grades provide the best reinforcing per unit cost. Above L/D 30:1, fiber breakage during processing becomes significant, reducing the realized aspect ratio in the cured part. The optimal grade depends on the mixing energy: lower-shear processes (casting, RTM) better preserve high aspect ratio, while high-shear mixing (compounding, injection molding) works better with L/D 10:1–15:1.
Direct Contact
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