Wollastonite Acicular (High Aspect Ratio)

CAS 13983-17-0In StockSample available

Key Features

  • High aspect ratio (20:1–30:1) for near-fiber-level reinforcing efficiency
  • 40–70% flexural modulus improvement at 20–40 wt% in UPR/epoxy
  • Superior crack bridging and fracture toughness improvement
  • Better dimensional stability and shrinkage control vs. short fiber grade
  • Silane surface treatment available for maximum stress transfer efficiency

High-aspect-ratio acicular wollastonite features length-to-diameter ratios of 20:1 to 30:1, significantly exceeding the reinforcing efficiency of standard short-fiber wollastonite. This extreme needle-like morphology enables load transfer mechanisms approaching those of short glass fiber while retaining the processing advantages and cost benefits of mineral fillers.

At L/D ratios of 20:1 or higher, wollastonite needles can achieve flexural modulus improvements of 40–70% in UPR and epoxy systems at 20–40 wt% loading, with tensile strength improvements of 20–35%. The high aspect ratio also provides superior dimensional stability and shrinkage reduction compared to standard grades, which is critical in precision-molded engineering composites and structural panels.

Acicular wollastonite's reinforcing mechanism is analogous to short glass fiber: under tensile loading, the long needles bridge micro-cracks and redistribute stress, delaying crack propagation and improving fracture toughness. This makes high-aspect-ratio wollastonite valuable in FRP profiles for construction, structural pultrusion compounds, and injection-molded engineering composites where impact resistance alongside stiffness is required. Surface treatment with aminosilane is recommended to maximize stress transfer efficiency between the wollastonite surface and the resin matrix.

Specifications

ParameterValue
AppearanceWhite needle-like crystals
Mohs hardness4.5–5.0
BET surface area4–8 m²/g
CaSiO₃ content≥ 97%
Moisture content≤ 0.3%
Whiteness (R457)≥ 92%
Aspect ratio (L/D)20:1 – 30:1
pH (5% suspension)9.5–10.5
Median fiber length~100–150 µm
Median fiber diameter~5–8 µm

Applications

High-stiffness structural FRP profiles and pultrusion compoundsEngineering composite injection molding with improved modulusPrecision-molded thermoset parts requiring minimal shrinkageAnti-corrosion coating primers with crack-bridging reinforcementFriction composites and brake pad formulations

FAQ

Higher aspect ratio wollastonite provides better reinforcement efficiency, up to a point. L/D 20:1–30:1 grades provide the best reinforcing per unit cost. Above L/D 30:1, fiber breakage during processing becomes significant, reducing the realized aspect ratio in the cured part. The optimal grade depends on the mixing energy: lower-shear processes (casting, RTM) better preserve high aspect ratio, while high-shear mixing (compounding, injection molding) works better with L/D 10:1–15:1.

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