Dispersing Agent for Mineral Fillers in Thermoset Resins
Key Features
- Reduces viscosity of high-filler-loading thermoset compounds by 50–80%
- Prevents filler sedimentation in liquid resin storage and handling
- Polymeric dispersant: steric stabilization maintains stable particle separation
- Critical for ATH-filled FR epoxy (100–200 phr ATH) to maintain processing viscosity
- Select acid or base anchor type to match filler surface chemistry
Dispersing Agent for Mineral Fillers in Thermoset Resins is a polymeric wetting and dispersing additive formulated for stabilizing high-loading mineral fillers (ATH, calcium carbonate, talc, silica, kaolin, wollastonite) in liquid thermoset resin systems. Without dispersant, mineral fillers aggregate during mixing and settle rapidly from liquid resin — primary particles cluster into agglomerates that increase viscosity dramatically, reduce optical transparency in clear castings, and create non-uniform filler distributions that cause mechanical property variation in cured composites.
Polymeric dispersants function through a two-stage mechanism: the wetting segment (typically an acidic or basic anchoring group) adsorbs onto the mineral surface, while the stabilizing segment (a polymer chain compatible with the resin) extends into the resin matrix and provides electrosteric repulsion between particles. This steric stabilization prevents re-aggregation of the dispersed particles and maintains a stable, low-viscosity dispersion even at high filler loadings (50–75% by weight in ATH-filled resins).
In ATH-filled halogen-free flame retardant epoxy and UPR systems (ATH loading 100–200 phr), dispersant at 0.5–2.0% on filler weight is critical for maintaining processable viscosity. Without dispersant, ATH at 150 phr in liquid epoxy produces a paste-like compound too viscous for casting or molding; with dispersant, the same compound may be processed as a pourable liquid. Dispersant selection is critical — compatibility with the specific resin/hardener chemistry and the specific filler surface chemistry must be verified to avoid pot life reduction or cured property degradation.
Specifications
| Parameter | Value |
|---|---|
| Appearance | Clear to slightly hazy liquid |
| Flash point | >61°C (solvent-free grades) |
| Chemical type | Acidic or basic polymeric dispersant (polyester or polyacrylate anchor) |
| Solids content | 40–100% (solvent-free or solvent-based, grade dependent) |
| Typical dosage | 0.3–2.0% on filler weight |
| Density (20°C) | 0.980–1.100 g/cm³ |
| Viscosity (25°C) | 100–5000 mPa·s |
Applications
FAQ
ATH surface is slightly basic (pH ~9 in water). In epoxy systems, use a dispersant with an acidic anchoring group (polyacid or phosphate ester anchor) that adsorbs well on the basic ATH surface, with a polyester or polyether stabilizing chain compatible with the epoxy resin polarity. In UPR/styrene systems, the dispersant must also be compatible with styrene — some polyether dispersants swell or dissolve in styrene, reducing effectiveness. For UPR, modified fatty acid or polyacrylate dispersants with controlled HLB value for styrene compatibility are preferred. Always test dispersant selection by measuring viscosity of the filled resin compound before and after dispersion to confirm effectiveness.
Direct Contact
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