UV Absorber Liquid Benzotriazole (Tinuvin 384 Type)
Key Features
- Liquid at ambient temperature — no heating required, direct addition to gelcoat paste
- Long alkyl chain — lower migration and volatility vs. simpler liquid benzotriazoles
- 300–380 nm UV absorption range — optimal for UPR/VER/epoxy aromatic chromophore protection
- Excellent compatibility with both styrene-containing and styrene-free resin systems
- Simplified gelcoat manufacturing: add at room temperature before pigment dispersion
UV Absorber Liquid Benzotriazole (Tinuvin 384 type, CAS 127519-17-9) is a long-chain alkyl ester-modified benzotriazole UV absorber that is liquid at room temperature, providing superior ease of handling and dissolution compared to solid benzotriazole grades like Tinuvin 328 type. The liquid form eliminates the heating and dissolution steps required for solid UVAs, enabling direct addition to gelcoat pastes, liquid resin systems, and coating formulations at ambient temperature.
The liquid benzotriazole structure provides excellent compatibility with the full range of UPR, VER, and epoxy resin systems, including styrene-containing and styrene-free formulations. The longer alkyl chain of the 384 type provides lower migration and volatility than simpler liquid benzotriazoles, making it suitable for applications requiring sustained long-term UV protection. UV absorption spectrum covers 300–380 nm, providing strong protection against the wavelengths most responsible for photooxidation in aromatic polyester and epoxy chromophores.
In production gelcoat manufacturing, Tinuvin 384 type simplifies the manufacturing process by eliminating the heating step required to dissolve solid benzotriazole. It is pre-mixed into the gelcoat paste before pigment and thixotropic agent addition, ensuring uniform distribution. At 0.3–1.0 phr in gelcoat combined with 0.2–0.5 phr HALS, it provides comprehensive UV protection for 8–15 years in typical European outdoor exposure conditions. For extremely demanding applications (desert exposure, tropical marine), higher loadings and supplementary UV protection strategies may be needed.
Specifications
| Parameter | Value |
|---|---|
| Appearance | Clear yellow to amber liquid |
| CAS Number | 127519-17-9 |
| Chemical name | 2-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol, alkyl ester modified |
| State at 25°C | Liquid (no melting point) |
| Typical loading | 0.3–1.0 phr |
| Molecular weight | ~630 g/mol |
| UV absorption max | ~354 nm |
Applications
FAQ
Yes. Tinuvin 384 type liquid benzotriazole is compatible with both amine-cured and anhydride-cured epoxy systems. It should be added to the epoxy Part A (resin) component and mixed before addition of the hardener. The liquid form ensures fast, homogeneous dissolution. In epoxy floor coatings and topcoats exposed to sunlight, Tinuvin 384 type at 0.5–1.5% by weight prevents chalking, gloss loss, and yellowing. Note that all epoxy systems yellow to some extent under UV exposure; UVA slows but does not completely prevent this in bisphenol A epoxy systems. Aliphatic epoxy (cycloaliphatic, DGEBA-free) coatings with UVA provide better long-term clarity.
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